کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6601105 | 459308 | 2016 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical jet-cell for the in-situ generation of hydrogen peroxide
ترجمه فارسی عنوان
سلول جت الکتروشیمیایی برای تولید در محل پراکسید هیدروژن
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کلمات کلیدی
آب اکسیژنه، الکترود انتشار گاز، سلول الکتروشیمیای جت، کربن احساس،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
In this work, a proof of concept of a novel reactor design for the in-situ electrochemical production of H2O2 from oxygen reduction reaction is presented for the first time. The innovative design incorporates a venturi-based jet aerator to supply atmospheric oxygen without additional energy consumption to a 3D flow-through modified carbon felt (CF) cathode. Preliminary experiments confirmed that electro-generation of hydrogen peroxide is possible in a system as the one proposed. Comparison with a flow-by cell with a gas diffusion cathode under similar conditions revealed that current efficiency towards hydrogen peroxide accumulation is even higher (72 vs 65% at 1Â h) than in the case of the conventional system. Jet aerator stands as a promising oxygen supply thanks to its excellent performance and both low investment cost and energy consumption. Considering all the above, the electrochemical jet cell stands as a rather promising design for the efficient hydrogen peroxide electro-generation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 71, October 2016, Pages 65-68
Journal: Electrochemistry Communications - Volume 71, October 2016, Pages 65-68
نویسندگان
J.F. Pérez, J. Llanos, C. Sáez, C. López, P. Cañizares, M.A. Rodrigo,