کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6669802 1427285 2018 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Heck-type olefination and Suzuki coupling reactions using highly efficient oxacalix[4]arene wrapped nanopalladium catalyst
ترجمه فارسی عنوان
آلکالین نوعی هک و واکنش های اتصال سوسوکی با استفاده از کاتالیزور نانوپلاالید هیدروژن پیچیده اکساکالیکس [4]
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
A simple one-pot method is used for the synthesis of water dispersible and stable palladium nanoparticles (PdNps) where oxacalix[4]arene dihydrazide (OXDH) is used as both a reducing and capping agent. The OXDH-PdNps have been characterized by UV-Visible spectroscopy, Fourier transform infrared (FT-IR), transmission electron microscopy (TEM), energy‐dispersive X‐ray spectroscopy (EDX), powder X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The OXDH-PdNps are spherical in shape with an average size of 3-4 nm and well crystallized in a face centered cubic structure. The capping of the OXDH ligand on the nanoparticles surface was evaluated using FT-IR. The OXDH-PdNps have been used in carbon-carbon coupling reactions, namely, the Suzuki-Miyaura and Mizoroki-Heck reactions. Both of the reactions are carried out under phosphine-free conditions to provide better yields. The nanocatalyst can be easily recovered and reused for six consecutive catalytic cycles without any significant loss in its catalytic activity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Saudi Chemical Society - Volume 22, Issue 5, July 2018, Pages 558-568
نویسندگان
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