کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6669866 | 1427288 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Fe-Co/sulfonated polystyrene as an efficient and selective catalyst in heterogeneous Baeyer-Villiger oxidation reaction of cyclic ketones
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
A highly efficient catalyst Fe-Co/sulfonated polystyrene (Fe-Co/SPS) was introduced and synthesized, which catalyzed BV oxidation of ketones with aqueous hydrogen peroxide to give the corresponding lactones in high yield and selectivity. Solid acid catalyst of Fe-Co/SPS has been prepared by using the 98-wt% sulfuric acid as the sulfonating agent and CoCl2 combined FeCl3 as sources of metal ions. Various physical-chemical characterizations including FT-IR, XRD, SEM and TGA, revealed that bimetallic ions Fe3+-Co2+ species in the sulfonated polystyrene framework were responsible for the catalytic activities. The BV reaction catalyzed by Fe-Co/SPS highlighted the special effects between metal ions and protonic acids as well as solvent-free heterogeneous catalytic oxidation with excellent conversion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Saudi Chemical Society - Volume 22, Issue 2, February 2018, Pages 129-135
Journal: Journal of Saudi Chemical Society - Volume 22, Issue 2, February 2018, Pages 129-135
نویسندگان
Yingting Wang, Jiangfeng Huang, Xiaomeng Xia, Xinhua Peng,