کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
672485 887507 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of layered cathode materials Li[CoxNiyMn1−x−y]O2 from layered double hydroxide precursors
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
Synthesis of layered cathode materials Li[CoxNiyMn1−x−y]O2 from layered double hydroxide precursors
چکیده انگلیسی
Cathode materials Li[CoxNiyMn1−x−y]O2 for lithium secondary batteries have been prepared by a new route using layered double hydroxides (LDHs) as a precursor. The resulting layered phase with the α-NaFeO2 structure crystallizes in the rhombohedral system, with space group R-3m having an interlayer spacing close to 0.47 nm. X-ray photoelectron spectroscopy (XPS) was used to measure the oxidation states of Co, Ni and Mn. The effects of varying the Co/Ni/Mn ratio on both the structure and electrochemical properties of Li[CoxNiyMn1−x−y]O2 have been investigated by X-ray diffraction and electrochemical tests. The products demonstrated a rather stable cycling behavior, with a reversible capacity of 118 mAh/g for the layered material with Co/Ni/Mn = 1/1/1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Particuology - Volume 8, Issue 3, June 2010, Pages 202-206
نویسندگان
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