کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
672871 | 1459469 | 2015 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of incongruent crystallization on glass-liquid transition features of a bulk metal glass
ترجمه فارسی عنوان
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کلمات کلیدی
کریستالیزاسیون ناپیوسته، انتقال شیشه، عینک آلیاژهای فلزی، نوسانات ساختاری،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
چکیده انگلیسی
It is known that most multi-component glasses cold-crystallize incongruently on heating through the temperature range of their ultraviscous melt. If the incongruent melt's composition changes with time, its viscosity, η, and the glass-liquid transition temperature, Tg, would change. Since the η, relaxation time, and expansion coefficient of a liquid in its partially crystallized mixture cannot be determined, we used scanning calorimetry to study the liquid-glass-liquid transition during thermal cycling of the incongruently crystallizing Ce66Al10Cu20Co4 glass. Its Tg is 358 K for 20 K/min and 354 K for 10 K/min heating rates, and its ultraviscous melt crystallized incongruently when heated beyond the hysteresis peak of its heat capacity scan. Its sample that had been aged for nine years at ambient conditions had a higher crystallization-onset temperature than an un-aged sample. Delayed enthalpy gain on heating of the aged glass is â¼1/5th of the enthalpy lost on its crystallization. Crystallization of the melt occurred on both the heating and cooling paths of a thermal cycle and Tg of the un-aged glass increased as the volume fraction of the compositionally different glass, fgl, decreased. The increase was by 8 K after the 24th cycle of 20 K/min, and by 11 K after the 13th cycle of 10 K/min cooling-heating. The highest Tg values reached differed by â¼1 K, which indicates that closely similar Tgs may be reached if the total time period for thermal cycling (at different rates) is kept the same. As fgl approached its limiting low value, increase in Tg per cycle itself increased, and the Tg-endotherm became unusually broad, which we attribute to diverse energies of interactions between the incongruent liquid and the crystal-surface atoms that dominate at the lowest fgl.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 615, 10 September 2015, Pages 72-80
Journal: Thermochimica Acta - Volume 615, 10 September 2015, Pages 72-80
نویسندگان
D.P.B. Aji, G.P. Johari,