Positive influence of expanded graphite on the physical behavior of phase change materials based on linear low-density polyethylene and paraffin wax

• Materials consisting of 50 wt.% of wax had sufficient mechanical strength.
• The amount of absorbed energy is proportional to the wax content.
• Graphite significantly increased thermal conductivity of materials.
• Graphite significantly reduced the wax loss from materials.

The preparation of Phase Change Materials (PCM) with improved thermal conductivity, based on linear low-density polyethylene (LLDPE), paraffin wax with a melting point of approximately 42 °C and expanded graphite as well as the investigation of their physical behavior is reported in this paper.The absorption of heat energy is realized by phase transitions in the wax structure, i.e., solid–solid transitions between different crystalline structures of wax and, primarily, by a solid–liquid transition. An estimate of the total heat energy that can be reversibly absorbed or released by the designed materials was determined using Differential Scanning Calorimetry (DSC).The improvement in the thermal conductivity of the polymeric materials was obtained by incorporating expanded graphite into the blends. Expanded graphite has a reinforcing effect on the PCM, resulting in an increase in the toughness (Young’s modulus) Significant amounts of wax are leached from the samples, and a higher wax content also results in more wax leakage. Graphite significantly reduces the wax loss from the samples.