Synthesis, thermodynamic properties and antibacterial activities of lanthanide complexes with 3,5-dimethoxybenzoic acid and 1,10-phenanthroline

• Four novel complexes ([Ln(3,5-DmeoxBA)3(phen)]2 were synthesized and characterized.
• The thermal decomposition processes of the title complexes were studied using the TG/DSC–FTIR coupling techniques.
• The heat capacities of the complexes were measured by (DSC).
• The antibacterial action of the four complexes on Escherichia coli, Staphylococcus aureus and Candida albicans were studied.

Four lanthanide complexes with a general formula [Ln(3,5-DmeoxBA)3(phen)]2 (Ln = Tb(1), Dy(2), Er(3), Yb(4); 3,5-DmeoxBA = 3,5-dimethoxybenzoic acid; phen = 1,10-phenanthroline) were synthesized and characterized by elemental analysis, infrared spectra (IR), and thermogravimetric, differential scanning calorimetry techniques, combined with Fourier transform infrared (TG/DSC–FTIR) technology. The thermal decomposition processes of the four complexes were investigated by TG/DSC–FTIR techniques. Heat capacities were measured by DSC. The values of the experimental heat capacities were fitted to a polynomial equation with the least-squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions (HT − H298.15 K), (ST − S298.15 K), and (GT − G298.15 K) were calculated. The antibacterial action of the four complexes on bacteria and fungus such as Escherichia coli, Staphylococcus aureus and Candida albicans were studied by filter paper approach. The luminescent properties of the complexes 1 and 2 were also studied.

Four novel complexes ([Ln(3,5-DmeoxBA)3(phen)]2 (Ln = Tb(1), Dy(2), Er(3), Yb(4); 3,5-DmeoxBA = 3,5-dimethoxybenzoic acid; phen = 1,10-phenanthroline))were synthesized and characterized by elemental analysis, IR and TG/DSC-FTIR technology. Heat capacities of the four complexes were measured by differential scanning calorimetry (DSC). The antibacterial action of the four complexes on bacteria and fungus such as Escherichia coli, Staphylococcus aureus and Candida albicans were studied by filter paper approach.Figure optionsDownload as PowerPoint slide