کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
673922 | 1459533 | 2013 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enthalpies of solution of L-phenylalanine in aqueous solution of amides at 298.15Â K
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The enthalpies of solution ÎsolHm have been determined for L-phenylalanine in aqueous solutions of formamide (FA), N-methylformamide (MFA), N,N-dimethylformamide (DMF) and N,N-dimethylacetamide (DMA). The measurements have been made at 298.15 K and mole fraction of amide x2 = (0-0.4) on the precise isothermic calorimeter. The results obtained have been used to calculate the standard enthalpies of solution (ÎsolH°) and transfer (ÎtrH°) of L-phenylalanine from water into mixtures as well as the enthalpy coefficients of pairwise interaction (hxy) of the solute with amide in aqueous media. The interrelation between enthalpy characteristics of dissolution (transfer) of L-phenylalanine and the composition of (water + amide) binary mixtures has been established. Contributions of the amides properties (molar volume, dipolarity/polarizability, acidity and basicity) to the energy of pairwise interactions have been estimated quantitatively by means of a modified Kamlet-Taft equation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 551, 10 January 2013, Pages 145-148
Journal: Thermochimica Acta - Volume 551, 10 January 2013, Pages 145-148
نویسندگان
Valeriy I. Smirnov, Valentin G. Badelin,