کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
674153 | 1459545 | 2012 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Miscibility, crystallization and mechanical properties of biodegradable blends of poly(l-lactic acid) and poly(butylene succinate-b-ethylene succinate) multiblock copolymer Miscibility, crystallization and mechanical properties of biodegradable blends of poly(l-lactic acid) and poly(butylene succinate-b-ethylene succinate) multiblock copolymer](/preview/png/674153.png)
Poly(l-lactic acid) (PLLA) is regarded as one of the most promising biobased and biodegradable polymers. However, its application was restricted due to the brittle nature. In the present study, PLLA was blended with a novel biodegradable flexible multiblock copolymer, poly(butylene succinate-b-ethylene succinate) (PBES) to produce new biodegradable materials. PLLA/PBES blends with different composition were prepared by solution blending and casting method with chloroform as a mutual solvent. Miscibility, crystallization behavior, and mechanical properties of the blends were investigated by differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), and tensile tests. The results indicated that PLLA and PBES showed limited miscibility in the amorphous phase. The crystallization rate of PLLA was accelerated with the increase of PBES in the blends while the crystallization mechanism did not change. The results of tensile tests suggest that the blends showed longer elongation at break than neat PLLA. The elongation at break of PLLA was obtained to be 10%, and those of PLLA/PBES 80/20, 60/40, 40/60 and 20/80 were 29, 110, 442, and 455%, respectively.
► The blend of PLLA and PBES showed limited miscibility.
► The crystallization rate of PLLA was accelerated by blending with PBES.
► The crystal structures of PLLA and PBES did not change.
Journal: Thermochimica Acta - Volume 539, 10 July 2012, Pages 16–22