کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
675179 | 1459612 | 2008 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal solid-solid interactions and physicochemical properties of NiO/Fe2O3 system doped with K2O
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Thermal solid-solid interactions and physicochemical properties of NiO/Fe2O3 system doped with K2O Thermal solid-solid interactions and physicochemical properties of NiO/Fe2O3 system doped with K2O](/preview/png/675179.png)
چکیده انگلیسی
The effects of calcination temperature and doping with K2O on solid-solid interactions and physicochemical properties of NiO/Fe2O3 system were investigated using TG, DTA and XRD techniques. The amounts of potassium, expressed as mol% K2O were 0.62, 1.23, 2.44 and 4.26. The pure and variously doped mixed solids were thermally treated at 300, 500, 750, 900 and 1000 °C. The catalytic activity was determined for each solid in H2O2 decomposition reaction at 30-50 °C. The results obtained showed that the doping process much affected the degree of crystallinity of both NiO and Fe2O3 phases detected for all solids calcined at 300 and 500 °C. Fe2O3 interacted readily with NiO at temperature starting from 700 °C producing crystalline NiFe2O4 phase. The degree of reaction propagation increased with increasing calcination temperature. The completion of this reaction required a prolonged heating at temperature >900 °C. K2O-doping stimulates the ferrite formation to an extent proportional to its amount added. The stimulation effect of potassium was evidenced by following up the change in the peak height of certain diffraction lines characteristic NiO, Fe2O3, NiFe2O4 phases located at “d” spacing 2.08, 2.69 and 2.95 Ã
, respectively. The change of peak height of the diffraction lines at 2.95Â Ã
as a function of firing temperature of pure and doped mixed solids enabled the calculation of the activation energy (ÎE) of the ferrite formation. The computed ÎE values were 120, 80, 49, 36 and 25Â kJÂ molâ1 for pure and variously doped solids, respectively. The decrease in ÎE value of NiFe2O4 formation as a function of dopant added was not only attributed to an effective increase in the mobility of reacting cations but also to the formation of potassium ferrite. The calcination temperature and doping with K2O much affected the catalytic activity of the system under investigation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 470, Issues 1â2, 10 April 2008, Pages 18-26
Journal: Thermochimica Acta - Volume 470, Issues 1â2, 10 April 2008, Pages 18-26
نویسندگان
W.M. Shaheen,