کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6769376 | 512474 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen generation from Al/NaBH4 hydrolysis promoted by Co nanoparticles and NaAlO2 solution
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Hydrogen generation from Al/NaBH4 hydrolysis promoted by Co nanoparticles and NaAlO2 solution Hydrogen generation from Al/NaBH4 hydrolysis promoted by Co nanoparticles and NaAlO2 solution](/preview/png/6769376.png)
چکیده انگلیسی
This study evaluated hydrogen generation through the hydrolysis of an Al/NaBH4/Co/NaAlO2 system. Hydrogen generation performance can be altered by changing the Al/NaBH4 mass ratios, Co amount and NaAlO2 concentration. The optimized composite can achieve a hydrogen yield of more than 90% within 30Â min. Thus, a high hydrogen generation amount and a stable solution pH were achieved. The kinetic analysis results of the Al/NaBH4/Co/NaAlO2 system show that the hydrolysis kinetic is affected by composition design. An activation energy of 53.3Â kJ/mol was obtained from 0.2Â g Al/0.2Â g NaBH4/0.06Â g Co nanoparticles/4Â mL 0.4Â M NaAlO2 solution, which confirms the control exerted by the chemical step. The improved hydrogen generation performance is attributed to the interaction of Al/NaBH4 hydrolysis and the synergistic catalytic effect of Co nanoparticles and NaAlO2. Thus, the mechanism that unifies the behavior of Al/NaBH4 hydrolysis, which is activated by Co nanoparticles and NaAlO2, is presented. As a potential hydrogen source, the Al/NaBH4/Co/NaAlO2 system can be applied for portable fuel cells with high hydrogen generation density and low cost compared with a conventional NaBH4 alkaline solution.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Renewable Energy - Volume 60, December 2013, Pages 637-642
Journal: Renewable Energy - Volume 60, December 2013, Pages 637-642
نویسندگان
Mei-qiang Fan, Yu Wang, Rui Tang, Da Chen, Wei Liu, Guang Lei Tian, Chun Ju Lv, Kang-ying Shu,