کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7044459 1457002 2013 25 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Removal of glyphosate from water by electrochemically assisted MnO2 oxidation process
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Removal of glyphosate from water by electrochemically assisted MnO2 oxidation process
چکیده انگلیسی
Glyphosate, one of the organophosphate herbicides, has been widely used in the word. The removal of glyphosate was comparatively investigated by MnO2 oxidation, electrochemical oxidation, and electrochemically assisted MnO2 oxidation (electro-MnO2) processes. The effects of MnO2 dosage, current density, and solution pH on glyphosate removal and Mn2+ release were examined. The results indicated that the removal of glyphosate by MnO2 oxidation favored acidic pH conditions and a large portion of Mn2+ ions were released from MnO2. With the electro-MnO2 process using RuO2/TiO2 coated titanium mesh as both anode and cathode, glyphosate removal was significantly promoted and most of the released Mn2+ ions were oxidatively reverted to MnO2, which in turn enhanced the removal of glyphosate. Solution pH exerted an insignificant effect on glyphosate removal in the electro-MnO2 process. Major reaction intermediates including sarcosine, glycine, and PO43- were indentified in the initial phase of the MnO2 oxidation and electro-MnO2 processes. Glycine was further decomposed to glycolic acid and NH3-N in the MnO2 oxidation process; in contrast, glycine was oxidized into oxamic acid, glycolic acid and N-contained intermediates, and N-contained intermediates could be finally oxidized into acetic acid, NH3-N and NO3--N in the electro-MnO2 process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 117, 30 September 2013, Pages 30-34
نویسندگان
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