کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7145923 | 1462076 | 2015 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Amino-naphthoquinone and its metal chelates for selective sensing of fluoride ions
ترجمه فارسی عنوان
آمینو نفتوکینون و کلات فلزی آن برای سنجش انتخاب یونهای فلوراید
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی
The fluoride ion sensing ability of 2-(2-(dimethylamino)ethylamino)-3-chloronaphthalene-1,4-dione (R1) and its metal chelates viz. [Cu(R1)Cl2], [Co(R1)Cl2].3H2O, [Zn(R1)Cl2] and [Ni(R1)Cl2] was studied through visual detection experiment, UV-Vis, fluorescence and 1H NMR titrations. The receptors were highly selective and sensitive for distinguishing fluoride ions from other common anions through a conspicuous change of UV-Vis and fluorescence spectra. The sensing mechanism, as confirmed by 1H NMR titration, involves formation of H-bond between the N-H moiety and F-ions. The coordination of metal ions was found to increase the H-bond donor ability of the receptor unit (NH). The binding constant for the [Zn(R1)Cl2] + Fâ complex was found to be 6.2 Ã 104 Mâ1 which is 15 times higher than that of R1 + Fâ complex. The sensing mechanism was further supported by electro chemical studies and DFT calculations using Gaussian 03 program. The detection limits of the probes in the determination of Fâ ions were found to 0.05-0.4 μM, which are lower than the World Health Organization (WHO) permissible level (1.5 mg Lâ1).The test strips prepared using [Zn(R1)Cl2] was found to impart striking colour change instantaneously with F-ions in water.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 215, August 2015, Pages 544-552
Journal: Sensors and Actuators B: Chemical - Volume 215, August 2015, Pages 544-552
نویسندگان
C. Parthiban, Kuppanagounder P. Elango,