کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7146390 | 1462087 | 2014 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of l-glutathione-capped-ZnSe quantum dots for the sensitive and selective determination of copper ion in aqueous solutions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis of l-glutathione-capped-ZnSe quantum dots for the sensitive and selective determination of copper ion in aqueous solutions Synthesis of l-glutathione-capped-ZnSe quantum dots for the sensitive and selective determination of copper ion in aqueous solutions](/preview/png/7146390.png)
چکیده انگلیسی
l-Glutathione capped (GSH) ZnSe quantum dots (QDs) have been synthesized as a fluorescence ions probes for ultrasensitive Cu (II) detection. These QDs surface decoration with glutathione shells can be directly applied without previous treatment. The fluorescence quenching of the GSH-capped-ZnSe QDs depends on the concentration, pH values and reaction time of the Cu2+ solution. Based on the effective electron transfer from GSH to Cu2+ and the surface ligand stripping occurs onto the surface of ZnSe QDs, it results in the reduction of Cu2+ to Cu+ and increment of surface defection on the surface of the QDs. Under the optimum conditions, the detection limit of Cu2+ is 2 Ã 10â10 mol Lâ1. Meanwhile, the effect of foreign ions displays a low interference response in the detecting of Cu2+ ions. Moreover, based on the invariable absorption peak position and curtate luminescence lifetime of ZnSe QDs, the quenching process has also been confirmed to be a dynamic quenching procedure. With regard to the practical feasibility test of the fluorescent probe, a relative lower standard deviation (RSD) (â¤3%) and a high recovery rate demonstrate that the proposed simple method is sensitive, accurate and reliable.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 203, November 2014, Pages 35-43
Journal: Sensors and Actuators B: Chemical - Volume 203, November 2014, Pages 35-43
نویسندگان
Yongling Ding, Shirley Z. Shen, Huadong Sun, Kangning Sun, Futian Liu,