کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7147366 | 1462099 | 2014 | 33 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Conductivity of cerium doped BaFeO3âδ and applications for the detection of oxygen
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Conductivity of cerium doped BaFeO3âδ and applications for the detection of oxygen Conductivity of cerium doped BaFeO3âδ and applications for the detection of oxygen](/preview/png/7147366.png)
چکیده انگلیسی
The effect of Ce doping on the structure and the conductivity of BaFeO3 perovskite materials is investigated and the resulting materials are applied as oxygen sensors. The new perovskite family, Ba1âxCexFeO3âδ (x = 0, 0.01, 0.03, and 0.05), was prepared via a sol-gel method. Powder XRD indicates a hexagonal structure for BaFeO3 with a change to a cubic perovskite upon cerium doping at the A site. The solubility limit of Ce at the A site was experimentally determined to be between 5 and 7 mol%. Bulk, electronic and ionic conductivities of BaFeO3âδ and Ba0.95Ce0.05FeO3âδ were measured in air at temperatures up to 1000 °C. Cerium doping increases the conductivity throughout the entire temperature range with a more pronounced effect at higher temperatures. At 800 °C the conductivity of Ba0.95Ce.05FeO3âδ reaches 3.3 S/cm. Pellets of Ba0.95Ce.05FeO3âδ were tested as gas sensors at 500 and 700 °C and show a linear, reproducible response to O2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 191, February 2014, Pages 171-177
Journal: Sensors and Actuators B: Chemical - Volume 191, February 2014, Pages 171-177
نویسندگان
William D. Penwell, Javier B. Giorgi,