کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7158572 | 1462797 | 2018 | 15 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Simultaneous production of lignin and polysaccharide rich aqueous solutions by microwave-assisted hydrothermal treatment of rapeseed meal
ترجمه فارسی عنوان
تولید همزمان لیگانین و محلول های محلول غنی از پلی ساکارید با استفاده از روش هیدروترمال مایکروویو از غذای کلزا
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کلمات کلیدی
مایکروویو ها، غذای کلزا، ارزش گذاری زیست توده، لیگنین، اولیگوساکاریدها،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
چکیده انگلیسی
This work addresses a novel and green process for the co-production of lignin and oligosaccharides from rapeseed meal, examining the effects of the temperature (150-210â¯Â°C), reaction time (0-60â¯min) and catalyst amount (1-4â¯mol/L, CH3COOH) on the process. The yields to gas, liquid and solid varied by 0-18%, 22-64% and 34-74%, respectively. The solid consisted of high purity lignin (26-88â¯wt.%) together with unreacted cellulose (0-28â¯wt.%), hemicellulose (0-28â¯wt.%) and proteins (11-28â¯wt.%). Increasing the temperature and/or reaction time produced an increase in the liquid yield and a decrease in the solid yield due to the solubilisation of the cellulosic and hemicellulosic contents of the feedstock. Acetic acid exerted a positive catalytic effect, promoting the solubilisation of cellulose and hemicellulose and preventing humins formation. The relative amounts (wt.%) of C, H, O and N in the solid fraction shifted between 46-63, 5.8-6.4, 28-42 and 2-6, respectively. Py-GC/MS analysis revealed that the solid decomposed into phenols (1-19%), sugars (0-15%), N-compounds (0-31%), carboxylic acids (37-75%), hydrocarbons (4-20%) and furans (1-8%). The liquid phase comprised oligo- and mono/di-saccharides (33-51 C-wt.%, 0-3 C-wt.% and 0-6 C-wt.%) and carboxylic acids (40-62 C-wt.%). The progressive solubilisation of cellulose and hemicellulose produced an increase in the proportion of C together with a decrease in the amounts of H and O in the solid product, which also accounted for the increase and decrease observed in the proportions of phenols and sugars, respectively. An optimum was found at 186â¯Â°C using an acid concentration of 1â¯mol/L and a total reaction time of 2â¯min. These conditions maximise the solubilisation of cellulose and hemicellulose without altering the lignin content of the solid; thus allowing the selective and simultaneous production of high purity (85â¯wt.%) lignin together with a rich oligossacharide (51 C-wt.%) solution. The acid can be recovered from the sugar mixture, which not only improves the efficiency of the process but also allows the production of a pure saccharide (92 C-wt.%) product.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Energy Conversion and Management - Volume 165, 1 June 2018, Pages 634-648
Journal: Energy Conversion and Management - Volume 165, 1 June 2018, Pages 634-648
نویسندگان
Javier Remón, Avtar S. Matharu, James H. Clark,