کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7171034 1463466 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and development of a chemically modified bio-adhesive derived from soybean flour protein
ترجمه فارسی عنوان
آماده سازی و توسعه زیست چسب اصلاح شده شیمیایی مشتق شده از پروتئین آرد سویا
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی مکانیک
چکیده انگلیسی
In this study, the potential of chemically modified soybean flour (SF) to be used as a strong and water resistant adhesive for bonding plywood composites was investigated. SF, sodium hydroxide (NaOH), acetic anhydride (AA), and polyethylenimine (PEI) were used to prepare adhesive formulations. Solid content and viscosity of adhesives were measured. Formulations were characterized using FTIR and UV absorption spectra to evaluate chemical changes of adhesives during modification. Water resistance and shear strength of plywood samples were measured, as well. FTIR analysis indicated that NaOH denatures SF; therefore amino groups buried inside the compact protein structure become available. In an SF/acetic anhydride adhesive (ASF), reaction with AA converted amine and hydroxyl groups to less polar components i.e. amides and esters, respectively. Using PEI for adhesives resulted in improved bond strength and water resistance. In this case, FTIR analysis showed that primary and secondary amines in ASF/PEI/NaOH formulations had disappeared. This could be due to a reduction in amine concentration and the formation of amides resulting in the occurrence of cross linking reactions. Absorption spectra of PEI, SF/PEI, and acetylated formulations with PEI showed a shift of λ max to a shorter wavelength due to the modifications. Comparing the water resistance and the shear strength of plywood samples containing the above mentioned formulations, with ones based on phenol formaldehyde (PF), revealed that SF with NaOH, AA, and PEI had the best adhesion performance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Adhesion and Adhesives - Volume 71, December 2016, Pages 48-54
نویسندگان
, , , , ,