کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7214174 | 1469460 | 2018 | 28 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facile fabrication of POSS-Modified MoS2/PMMA nanocomposites with enhanced thermal, mechanical and optical limiting properties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A facile strategy was applied to transfer chemically exfoliated molybdenum disulphide (MoS2) nanosheets from aqueous medium to organic solvents. The MoS2 nanosheets were then modified by trisilanol-phenyl-POSS (T7POSS) which was confirmed by Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS) and Powder X-Ray Diffraction (PXRD). The modified MoS2 nanosheets were then incorporated into poly (methyl methacrylate) (PMMA) via a simple solution blending method. The Scanning Electron Microscope (SEM) and Transmission electron microscope (TEM) were employed to demonstrate the well-dispersion of nanosheets in polymeric matrix. Compared to neat PMMA, the decomposition temperatures (Td) and the half weight decomposition temperatures (Thalf) of POSS-MoS2/PMMA nanocomposites at nanosheets concentration of 0.2â¯wt% were dramatically increased by 35.2â¯Â°C and 35.3â¯Â°C, respectively. Meanwhile, according to the measurements of Dynamic Mechanical Analysis (DMA), the storage modulus at 30â¯Â°C is significantly improved by 5.2 times and the glass transition temperature (Tg) is also enhanced by 6.2â¯Â°C. Remarkably, POSS-MoS2/PMMA nanocomposites possess low optical limiting differential transmittance Tc (0.5%), low nonlinear optical absorption onset threshold FON (0.02â¯Jâ
cmâ2), low optical limiting threshold FOL (0.4â¯Jâ
cmâ2) and high nonlinear coefficient β (297â
cmâ¯GWâ1), highlighting their vast potential in the development of solid-state optical limiting materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Science and Technology - Volume 165, 8 September 2018, Pages 388-396
Journal: Composites Science and Technology - Volume 165, 8 September 2018, Pages 388-396
نویسندگان
Qiaobo Liao, Qi Zhang, Xuelin Wang, Xinle Li, Guoqing Deng, Zhen Meng, Kai Xi, Peng Zhan,