کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7215707 | 1469522 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hybrid polymer electrolyte composite with SiO2 nanofiber filler for solid-state dye-sensitized solar cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
SiO2 nanofibers were prepared by electrospinning method and incorporated as filler into a hybrid polymer matrix of poly(ethylene oxide) (PEO) and poly(vinylidene fluoride)-hexafluoropropylene (PVDF-HFP). The effectiveness of the SiO2 nanofiber-filled matrix as a polymer electrolyte for solid-state dye-sensitized solar cells (DSCs) was evaluated. The SiO2 nanofiber filler was found to increase the ionic conductivity, thereby improving the charge transport of the Iâ/I3â redox couple in the electrolyte. As a result, the efficiency of the DSCs was increased by up to 24% as compared with a pristine polymer electrolyte. The ionic conductivity was found to be greatest in the polymer electrolyte containing 0.01 g of SiO2 nanofiber filler, 9.90 Ã 10â4 s cmâ1, which represents a substantial increase over the 3.81 Ã 10â4 s cmâ1 of a pristine polymer electrolyte. Furthermore, the addition of 0.01 g of SiO2 nanofiber filler also produced the highest electron transport time of 1.47 ms, an electron recombination time of 29.41 ms, and a charge collection efficiency of 94.99%. The SiO2 nanofiber filler also greatly enhanced the interfacial stability between the polymer electrolyte and the semiconductor electrodes, with the hybrid polymer electrolyte containing 0.01 g of SiO2 nanofiber filler exhibiting both the lowest cell impedance (20.96 Ω) and the highest solar conversion efficiency (4.85%) in this study.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Science and Technology - Volume 103, 28 October 2014, Pages 100-105
Journal: Composites Science and Technology - Volume 103, 28 October 2014, Pages 100-105
نویسندگان
Xing Guan Zhao, En Mei Jin, Ju-Young Park, Hal-Bon Gu,