کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7215863 | 1469538 | 2013 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facile route to controlled iron oxides/poly(3,4-ethylenedioxythiophene) nanocomposites and microwave absorbing properties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Electromagnetic iron oxides/poly(3,4-ethylenedioxythiophene) (PEDOT) nanocomposites were successfully synthesized via a simple one-step method using FeCl3/ ammonium persulfate (APS) as the composite oxidants. The iron oxide nano-materials were formed in the polymer matrix. By simply adjusting the molar ratio of Fe3+ to Fe2+ (represented by [Fe3+]/[Fe2+] ratio), the composites were controlled to be α-FeOOH/PEDOT nanorods or γ-Fe2O3/PEDOT nanoparticles. Transmission electron microscope, X-ray diffraction and Fourier transform infrared used to characterize the morphologies and constitutes of the nanocomposites. The results suggested that both of α-FeOOH and γ-Fe2O3 were nanocrystals, which were coated by PEDOT to form a core-shell structure. The conductivities of the composites were in the range of 10â3 to 10â1  S/cm and the saturation magnetization varied from 5 emu/g to 46 emu/g correspondingly. Moreover, the composite exhibited excellent microwave absorbing property with a minimum reflection loss of about â44 dB when [Fe3+]/[Fe2+] ratio was 3. This study provides a novel method to realize the transformation of iron oxides under mild conditions and synthesize electromagnetic composites with controlled morphology and properties.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Science and Technology - Volume 87, 18 October 2013, Pages 14-21
Journal: Composites Science and Technology - Volume 87, 18 October 2013, Pages 14-21
نویسندگان
Wencai Zhou, Xiujie Hu, Shuyun Zhou, Jun Yan, Chenghua Sun, Ping Chen,