کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7223856 | 1470563 | 2018 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A comparative study of photocatalytic activity of ZnS photocatalyst for degradation of various dyes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A simple chemical precipitation method is used to synthesize the cubic phase of ZnS nanoparticles. The crystal structure, phase purity, surface morphology, optical and photo-luminescence properties, and photocatalytic activity of ZnS nanoparticles were studied using X-ray diffraction (XRD), fourier transform infrared (FTIR) spectra, Raman spectrometer, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), UV-vis spectrophotometer, fluorescence spectrophotometer and 721 spectrophotometer. XRD, FTIR, Raman and XPS analysis indicates that the ZnS nanoparticles has a cubic phase with the cell parameter aâ¯=â¯5.406â¯Ã
without the presence of any other impurities. SEM image shows that the average particle size of ZnS nanoparticles is about 40â¯nm. Optical properties and photoluminescence experiment confirmed that the Eg value is found to be 3.21â¯eV and the emission spectra are made up of four emission bands at 345, 408, 444 and 510â¯nm under excitation wavelength at 290â¯nm. Photocatalytic experiment results indicate that the pure ZnS nanoparticles exhibits an obviously enhanced photocatalytic activity for degradation MO, and MR dyes than degradation MB, and XO dyes due to the ZnS nanoparticles can easily degradation the NN bonds. Based on the electrochemical measurement and photocatalytic experiment, a possible photocatalytic mechanism for degradation of various dyes in presence of the ZnS nanoparticles are analyzed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optik - Volume 164, July 2018, Pages 345-354
Journal: Optik - Volume 164, July 2018, Pages 345-354
نویسندگان
Zhiyuan Ye, Linyan Kong, Feng Chen, Zhigang Chen, Yun Lin, Chengbao Liu,