کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
745064 | 894413 | 2009 | 8 صفحه PDF | دانلود رایگان |

1-Arylazo-5,5-dimethyl dipyrromethanes (azo-DPM's) have been synthesized by electrophilic substitution reactions of 5,5-dimethyl dipyrromethanes in aqueous solution in 23–68% yields. The solution phase binding studies of azo-DPM's have been investigated by naked eye, absorption and proton NMR spectroscopy. The receptors, appended with electron-withdrawing groups display enhanced affinity and selectivity for F−, H2PO4− and AcO− than electron-donating groups in different solvents. Furthermore, the solvatochromic responses of 2,5-bis(4′-nitrophenyl)azo-pyrrole have been examined by visual and UV–vis spectroscopy with or without structurally different anions in a variety of solvents. The present studies of anion receptors may be used in environmental sensors, molecular electronics and development of molecular switches.
Journal: Sensors and Actuators B: Chemical - Volume 141, Issue 1, 18 August 2009, Pages 116–123