کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
745232 | 1462112 | 2013 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Time-monitoring sensor based on oxygen diffusion in an indicator/polymer matrix Time-monitoring sensor based on oxygen diffusion in an indicator/polymer matrix](/preview/png/745232.png)
A time-monitoring sensor based on the oxidation of leuco methylene blue (LMB) to methylene blue (MB) was developed. The sensor changes its color from yellow to green in the presence of oxygen and was integrated into a poly(vinyl alcohol) matrix. The diffusion of the oxygen in the polymer matrix as well as the oxygen uptake due to the oxidation reaction determines the time monitoring of the sensor. A physical model has been developed that accounts for both the diffusion as well as the oxidation reaction. For this purpose, the reaction kinetics was determined experimentally. Moreover, the diffusion coefficient of oxygen was determined and concentration profiles in the polymer matrix modeled. Based on these modeling, the time sensor could be calibrated very precisely. This widely applicable, low-cost visual sensor is compatible with current technologies for the processing of plastics and can be integrated into different types of packaging, e.g. for application in freshness monitoring of consumer goods.
Journal: Sensors and Actuators B: Chemical - Volume 178, 1 March 2013, Pages 254–262