کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
746416 1462125 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ionic liquid thin layer EQCM explosives sensor
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Ionic liquid thin layer EQCM explosives sensor
چکیده انگلیسی

An integrated sensor that combines electrochemical and piezoelectric transduction mechanisms into a single miniaturized platform was developed and validated for the detection of nitro aromatic compounds such as ethyl nitrobenzene (ENB) and dinitrotoluene that are analogues of redox active explosives. An ionic liquid (IL) BMIBF4 was used as both the electrolyte and the sorption solvent for the two-dimensional electrochemical and piezoelectric gas sensors.The electrochemical behaviors of these nitro compounds in BMIBF4 were studied by cyclic voltammetry, differential pulse voltammetry and square wave voltammetry, in parallel. The electrochemical properties of these compounds resembled the electrochemical reduction processes in their aprotic solutions, showing first a reversible reduction process and then subsequently an irreversible reduction processes. The redox properties of these compounds also depend on the number of nitro groups and the position of the nitro groups on the benzene ring. Square wave voltammetry was used to quantitatively analyze the ENB in BMIBF4. Reduction peaks in the square wave voltammetric curves could be obtained when the concentrations were at ppm level. A small amount of moisture in the IL electrolyte did not significantly affect the redox behaviors. Piezoelectric quartz crystal microbalance (QCM) electrodes and the electrodes for amperometry were fabricated on a single piece of quartz plate. Detection of the volatile ENB vapor with this integrated EQCM chip was tested with both QCM and amperometric methods. The sensor's signal was related quantitatively to the ENB vapors adsorbed in BMIBF4 from air. Combining amperometric and QCM detection simultaneously can cross-validate the detection technology, reduce false positives and false negatives and increase the accuracy of the detection.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 140, Issue 2, 16 July 2009, Pages 363–370
نویسندگان
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