Effects of the cell thermal behavior and water phase change on a proton exchange membrane fuel cell performance

A two-dimensional, non-isothermal, electrochemical-transport using a fully coupled numerical model is developed for a proton exchange membrane fuel cell to investigate simultaneous water, heat transport phenomena and their effects on cell performance. The multiphase mixture formulation for the two-phase transport process is used, and developed model is treated as a single domain. This process is leading to a single set of conservation equations consisting of continuity, momentum, species, potential and energy for all regions of cell. The result indicates that flooding of porous cathode reduces the rate of oxygen transport to the cathode catalyst layer and causes an increase in cathode polarization. Also, flooding could effect current density distribution, where a slight abrupt change occurs in the slope of the local current density curve. The amount and location of condensation in the GDL cathode is directly related to the cell temperature, where the temperature difference predicted by this model is about 3.7 °C at 0.6 V. The maximum temperature occurs near the inlet and at interface between membrane/catalyst layers at cathode side where major heat generation takes place. The results are validated with experimental data available that are in good agreement.