کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7691438 1496012 2018 38 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of homogeneous acidic catalyst on mechanical strength of trishydrazone hydrogels: Characterization and optimization studies
ترجمه فارسی عنوان
اثر کاتالیزور اسیدی همگن بر مقاومت مکانیکی هیدروژل های ترشیدراسون: مطالعات توصیفی و بهینه سازی
کلمات کلیدی
ژلاتورهای مولکولی کم، سیستم خودمختار، کاتالیزور، قدرت مکانیکی، مدل سازی ریاضی،
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
چکیده انگلیسی
Characterization utilizing X-ray photoelectron spectroscopy (XPS) revealed the presence of all the expected elements found in trishydrazone hydrogels (3). Morphological study on confocal laser scanning microscopy (CLSM) and atomic force microscopy (AFM) revealed the branching and bundling of fibers that led hydrogels network as well as the presence of cross-linked nanofibrillar network structure. A three-factor three-level Box Behnken design was implemented to study the concurrent effects of three main variables (concentration of precursor; 10-20 mM, pH; 3-7, and concentration of buffer; 50-150 mM) on mechanical strength of hydrogels. Analysis of variance (ANOVA) was conducted to investigate the potential interactive and quadratic effects between these variables and revealed that interaction between the pH value and the concentration of buffer (X2X3) showed a significant effect on the response since the significance of the design model (p-value) was set at <0.05. Experimental results showed that acid catalyst at pH 5 had a significant effect on mechanical properties of hydrogels compared to uncatalyzed condition at pH 7 where the mechanical strength at pH 5 is almost 10 times higher than pH 7. The processing conditions that contributed to an optimum hydrogels setting were found at concentration of precursor = 20 mM, pH = 5 and concentration of buffer = 100 mM.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Arabian Journal of Chemistry - Volume 11, Issue 5, July 2018, Pages 635-644
نویسندگان
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