کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7762718 | 1500191 | 2018 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cyclodimerization of isocyanates promoted by one large vertex metallaborane
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
The 10-vertex Manganese-decaborane [nido-6-Mn(CO)3B9H13][NMe4] was found to act as an efficient catalyst for isocyanate cyclodimerization under photo-irradiation conditions. The reaction yields were comparable with other metal catalyst reported in literature. One of the products was characterized by X-ray crystallographic study and reaction mechanism was also proposed. The results are very encouraging as they represent first examples of a large metallaborane compound to catalyze the cyclodimerization of isocyanates.30
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 149, 15 July 2018, Pages 148-152
Journal: Polyhedron - Volume 149, 15 July 2018, Pages 148-152
نویسندگان
Pei Ma, James T. Spencer,