کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7762718 1500191 2018 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cyclodimerization of isocyanates promoted by one large vertex metallaborane
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Cyclodimerization of isocyanates promoted by one large vertex metallaborane
چکیده انگلیسی
The 10-vertex Manganese-decaborane [nido-6-Mn(CO)3B9H13][NMe4] was found to act as an efficient catalyst for isocyanate cyclodimerization under photo-irradiation conditions. The reaction yields were comparable with other metal catalyst reported in literature. One of the products was characterized by X-ray crystallographic study and reaction mechanism was also proposed. The results are very encouraging as they represent first examples of a large metallaborane compound to catalyze the cyclodimerization of isocyanates.30
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 149, 15 July 2018, Pages 148-152
نویسندگان
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