کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7764564 | 1500226 | 2016 | 15 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photochemical reactivity of a binuclear Fe(I)-Fe(I) hydrogenase model compound with cyano ligands
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Iron-iron hydrogenase model compounds have potential as hydrogen producing catalysts that are inexpensive and environmentally friendly. Many of these model compounds are dependent on light for activity but little is know about the photochemical intermediates or products that are formed and catalytically important. The photochemistry of μ-pdt-[Fe(CO)2CN]22â (2) is explored in acetonitrile and spectral changes in the IR support lost of CNâ. UV-Vis spectroscopy was used to determine quantum yields for the disappearance of 2, which was found to be 0.37 ± 0.04 in acetonitrile when irradiated with 365 nm light under nitrogen.87
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 114, 16 August 2016, Pages 306-312
Journal: Polyhedron - Volume 114, 16 August 2016, Pages 306-312
نویسندگان
Andrew Hunt, Jacob Barrett, Meghan McCurry, Carmen Works,