کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7764919 | 1500237 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Two novel oxomolybdenum(V)-trispyrazolylborate complexes: Synthesis, structure, and catalytic performance in the cyclohexane oxidation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Two novel oxomolybdenum(V)-trispyrazolylborate complexes: Synthesis, structure, and catalytic performance in the cyclohexane oxidation Two novel oxomolybdenum(V)-trispyrazolylborate complexes: Synthesis, structure, and catalytic performance in the cyclohexane oxidation](/preview/png/7764919.png)
چکیده انگلیسی
Two novel oxomolybdenum(V)-trispyrazolylborate complexes [(TpMoO)(μ2-O)2(MoOTp)](Tp = tris(pyrazolyl)borate) (1) and [(Tp4IMoOCl)(μ-O)(MoOClTp4I)](Tp4I = tris(4-iodinpyrazolyl)borate) (2) were synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. Their catalytic performances in cyclohexane (Cy) oxidation were studied. It is found that the catalytic performances of molybdenum(V) complexes 1 and 2 were far more better than the molybdenum(VI) complexes with the similar structure. The influence of the amount of H2O2, HNO3 and the solvents on the Cy oxidation were investigated too.138
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 102, 14 December 2015, Pages 386-393
Journal: Polyhedron - Volume 102, 14 December 2015, Pages 386-393
نویسندگان
Xin Liu, Na Xing, Jian Song, Qiong Wu, Zhidan Yan, Yan Zhang, Yongheng Xing,