کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7765026 | 1500237 | 2015 | 17 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Luminescent neutral lanthanide complexes of 5-aryl-2,2â²-bipyridine-6-carboxylic acids, synthesis and properties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Luminescent neutral lanthanide complexes of 5-aryl-2,2â²-bipyridine-6-carboxylic acids, synthesis and properties Luminescent neutral lanthanide complexes of 5-aryl-2,2â²-bipyridine-6-carboxylic acids, synthesis and properties](/preview/png/7765026.png)
چکیده انگلیسی
Phosphorescent lanthanide complexes of 4-aryl-1-(2-pyridyl)-6,7-dihydro-5H-cyclopenta[c]pyridine-3-carboxylic acids and 5-tolyl-2,2â²-bipyridine-6-carboxylic acid were prepared. The ligands were synthesized using the “1,2,4-triazine” methodology. In one case, the opportunity for copper complex preparation, followed by exchange of the metal cation from copper to europium to overcome synthetic difficulties, was demonstrated. The ability of tuning the properties of the complexes by means of varying the structure of the ligands was demonstrated. In particular, the introduction of the cyclopentene moiety allowed the preparation of highly soluble complexes in non-polar organic solvents.126
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 102, 14 December 2015, Pages 556-561
Journal: Polyhedron - Volume 102, 14 December 2015, Pages 556-561
نویسندگان
Alexey P. Krinochkin, Dmitry S. Kopchuk, Dmitry N. Kozhevnikov,