کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7765384 1500250 2015 23 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The versatility of pyridine-2,5-dicarboxylic acid in the synthesis of fac-M(CO)3 complexes (M = Re, 99mTc): Reactivity towards substitution reactions and derivatization after coordination to a metal
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
The versatility of pyridine-2,5-dicarboxylic acid in the synthesis of fac-M(CO)3 complexes (M = Re, 99mTc): Reactivity towards substitution reactions and derivatization after coordination to a metal
چکیده انگلیسی
Two new Re(I) tricarbonyl crystal structures are presented, fac-[NEt4][Re(2,5-PicoH)(CO)3(Br)] and fac-[NEt4][Re(2,5-PicoMe)(CO)3(Br)] and both illustrate a distorted octahedral arrangement. Methanol substitution kinetics is performed between fac-[NEt4][Re(2,5-PicoH)(CO)3(Br)] and various monodentate entering ligands. The functionalization on the backbone of the bidentate ligand is illustrated after the ligand is coordinated to the Re(I) metal center.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 89, 29 March 2015, Pages 122-128
نویسندگان
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