کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7765405 1500250 2015 20 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structure and magnetic properties of a cobalt(III) complex with redox-active 1-(2-pyridylazo)-2-phenanthrol (papl)
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Structure and magnetic properties of a cobalt(III) complex with redox-active 1-(2-pyridylazo)-2-phenanthrol (papl)
چکیده انگلیسی
We describe the structural, electronic and magnetic properties of a cobalt(III) complex with a redox-active ligand (papl). This work represents the first reported structural data for any trivalent complex with papl. We investigate the electronic properties of this complex by cyclic voltammetry and UV-Vis spectroscopy and observe LMCT states not present in divalent complexes with papl reported earlier. We also investigate the variable temperature magnetic susceptibility of the complex and observe significant temperature dependent magnetic properties.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 89, 29 March 2015, Pages 155-159
نویسندگان
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