کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7834041 | 1503526 | 2018 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structure transformations in thin films of CF3-CFH2 cryodeposites. Is there a glass transition and what is the value of Tg?
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Structure transformations in thin films of CF3-CFH2 cryodeposites. Is there a glass transition and what is the value of Tg? Structure transformations in thin films of CF3-CFH2 cryodeposites. Is there a glass transition and what is the value of Tg?](/preview/png/7834041.png)
چکیده انگلیسی
In the temperature range 16-100â¯K, IR spectrometric studies of thermally stimulated transformations in cryocondensed Freon 134a films were carried out. It was found that Freon 134a cryofilms, formed at Tâ¯=â¯16â¯K, under heating range from 70 to 90â¯K undergo multiple structural transformations of various nature. It was concluded that at a temperature of Tgâ¯=â¯72â¯K, takes place the glassy state transition to the supercooled liquid (G-SCL). At about Tâ¯=â¯78â¯K, crystallization of SCL begins the state of an orientationally disordered plastic crystal. At a transition temperature Ttransâ¯=â¯80â¯K, a second quasi-glass transition occurs from the state of the orientation glass to a plastic crystal with an ordered rotational subsystem. Within temperature range 83-85â¯K, a plastic crystal-monoclinic crystal phase transition takes place.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 446, 15 July 2018, Pages 196-200
Journal: Applied Surface Science - Volume 446, 15 July 2018, Pages 196-200
نویسندگان
Andrey Drobyshev, Abdurakhman Aldiyarov, Assel Nurmukan, Dmitriy Sokolov, Ainura Shinbayeva,