کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7837089 | 1504160 | 2018 | 28 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Second virial coefficient of bounded repulsive potentials
ترجمه فارسی عنوان
ضریب دوم وییرال پتانسیل بازدارنده محصور شده
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
Exact series expansion formulas are derived for the second virial coefficient, SVC, of a wide range of purely repulsive bounded potentials. The focus is on the consequences of the functional form, choice of disposable parameters, and temperature on the SVC characteristics. These include compressed and stretched exponential forms, and bounded inverse power (BIP) potentials, which are an extension of the inverse power system. The BIP have a quite different SVC temperature dependence to the exponential cases, characteristics which could be used to represent polymer based dispersed particles which are not accounted for by a gaussian. A new algebraic form of bounded potential is proposed whose SVC at high temperature tends to the Penetrable Sphere, but at low temperature to the BIP class.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 513, 24 September 2018, Pages 174-181
Journal: Chemical Physics - Volume 513, 24 September 2018, Pages 174-181
نویسندگان
D.M. Heyes,