کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7837140 1504163 2018 21 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Collective effect of light-induced and natural nonadiabatic phenomena in the dissociation dynamics of the NaI molecule
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Collective effect of light-induced and natural nonadiabatic phenomena in the dissociation dynamics of the NaI molecule
چکیده انگلیسی
Natural and light-induced nonadiabatic effects are ubiquitous in many photochemical and photophysical processes. Here we study the interplay between them when they are present simultaneously in a molecular system. Our showcase example is the NaI molecule. Solving the time-dependent nuclear Schrödinger equation the photodissociation rate and the angular distribution of the molecular photofragments are calculated and discussed at several resonant laser energies and intensities. Obtained results clearly demonstrate that the dissociation rate and the angular distribution of the NaI photofragments can be considered as clear fingerprint of a collective effect of light-induced and natural nonadiabatic phenomena.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 509, 15 June 2018, Pages 91-97
نویسندگان
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