Creep property of carbon and nitrogen free high strength new alloys

The carbon and nitrogen free new alloys which were composed of supersaturated martensitic microstructure with high dislocation density before the creep test have been investigated systematically. These alloys were produced from the new approach which raised creep strength by the utilization of the reverse transformed austenite phase as a matrix and intermetallic compounds such as Laves phase and mu-phase as precipitates during heating before the creep test. It is important that these alloys are independent of any carbides and nitrides as strengthening factors. The high temperature creep test over 700 °C exceeds 50,000 h, and the test is continuous. Creep behavior of the alloys is found to be different from that of the conventional high-Cr ferritic steels. The addition of boron to the alloy pulled the recrystallization temperature up in the high temperature, and it became a creep test in the un-recrystallization condition, and the creep property of high temperature over 700 °C was drastically improved. The minimum creep rates of Fe–Ni alloys at 700 °C are found to be much lower than those of the conventional high Cr ferritic heat resistant steels, which is due to fine dispersion strengthening useful even at 700 °C in these alloys. As a result it became clear that the value for 100,000 h was exceeded at 700 °C and 100 MPa calculated from the Larson-Miller parameter at C = 20.