کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7889332 | 1509860 | 2018 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Largely enhanced thermal conductivity of HDPE/boron nitride/carbon nanotubes ternary composites via filler network-network synergy and orientation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Largely enhanced thermal conductivity of HDPE/boron nitride/carbon nanotubes ternary composites via filler network-network synergy and orientation Largely enhanced thermal conductivity of HDPE/boron nitride/carbon nanotubes ternary composites via filler network-network synergy and orientation](/preview/png/7889332.png)
چکیده انگلیسی
In recent years, hybrid fillers with different dimension are frequently used to improve the thermal conductivity of polymer/filler composites. While the combined effect of hybrid filler and orientation on the thermal conductivity of polymer/filler composites has rarely reported. In this work, high density polyethylene (HDPE)/boron nitride (BN)/carbon nanotubes (CNT) ternary composites were prepared by melt blending then hot rolled to obtain oriented sheets. The thermal conductivity and internal structure of the obtained sheets were investigated and compared with those obtained by hot-pressed sheets with random distributed structure. Two representative systems were used, the one is that BN content is low and forms the isolated dispersions (using HDPE/5BN/CNT composites with 5â¯wt% of BN as example), the other one is that BN content is high and forms network structure (using HDPE/25BN/CNT composites with 25â¯wt% of BN as example). For hot-pressed samples, no synergy between BN and CNT was found for HDPE/5BN/CNT system with BN dispersed in isolation in HDPE matrix, while an obvious increase of thermal conductivity was seen for HDPE/25BN/CNT system with BN network formation in HDPE matrix, and a 300% increase of thermal conductivity could be achieved as 3â¯wt% of CNT was added, compared with that of net HDPE. For hot-rolled samples, an increase of thermal conductivity was observed for both HDPE/5BN/CNT and HDPE/25BN/CNT ternary composites by adding CNT into the composites, suggesting the importance of filler orientation in the enhancement of thermal conductivity in polymer/filler composites with hybrid filler. The combined effect of hybrid filler and orientation could result in a further increase of thermal conductivity and 600% increase of thermal conductivity could be achieved. Finally, based on the analysis of internal structure of prepared samples as obtained by SEM observation, rheology and XRD measurements, a possible mechanism for the enhancement of thermal conductivity via hybrid and orientation was proposed. Our work is important and could shed light for the preparation of polymer composites with super thermal conductivity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Part A: Applied Science and Manufacturing - Volume 112, September 2018, Pages 32-39
Journal: Composites Part A: Applied Science and Manufacturing - Volume 112, September 2018, Pages 32-39
نویسندگان
Junjin Che, Mengfan Jing, Dingyao Liu, Ke Wang, Qiang Fu,