کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7889463 | 1509860 | 2018 | 29 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nanocellulose reinforced P(AAm-co-AAc) hydrogels with improved mechanical properties and biocompatibility
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
Carboxylate modified cellulose nanofibril (CNF) was used to reinforce poly(acrylamide-co-acrylic acid) (P(AAm-co-AAc)) hydrogel via in-situ polymerization. With introduction of Fe3+-carboxylate complexation, a dual cross-linking network structure in the P(AAm-co-AAc)/CNF hydrogels was constructed, i.e. the covalently cross-linked acrylic components forming a macromolecular network, and the noncovalently COOâ-Fe3+ ionic coordination bonds acting as secondary cross-linking points. The microstructure of the hydrogels was characterized by scanning electron microscopy (SEM). By incorporating 0.6â¯wt% CNF, the elastic modulus, tensile strength and toughness of P(AAm-co-AAc) hydrogel were improved by 240%, 104% and 51%, respectively. The addition of CNF also enhanced the energy dissipation in loading and unloading tests. P(AAm-co-AAc)/CNF nanocomposite hydrogels showed water content (70-80%) comparable with that in human cartilage (75%). The biocompatibility tests suggested that P(AAm-co-AAc)/CNF had no toxicity to cells and cells can adhere and proliferate well on the surface, making it suitable for biomedical and tissue engineering applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Part A: Applied Science and Manufacturing - Volume 112, September 2018, Pages 395-404
Journal: Composites Part A: Applied Science and Manufacturing - Volume 112, September 2018, Pages 395-404
نویسندگان
Shu Huang, Zhan Zhao, Chuang Feng, Edwin Mayes, Jie Yang,