کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7890661 | 1509884 | 2016 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Excellent dielectric properties of PVDF-based composites filled with carbonized PAN/PEG copolymer fibers
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Weak interfacial bonding between carbon materials and polymer matrix impedes the formation of homogeneous composites, challenging to the enhancement of dielectric properties of such systems. In this work, we designed novel carbonized polyacrylonitrile/polyethylene glycol copolymer fibers (CPCFs) and then used them as fillers to enhance the dielectric properties of poly(vinylidene fluoride) (PVDF)-based composites. These CPCFs are rich in nitrogen (8.55%) and oxygen (3.94%) atoms on the surface of them. The results of molecular dynamic (MD) simulations indicate that the existence of these atoms significantly increase the interaction energy between CPCFs and PVDF matrix from â45.13Â kcal/mol to â62.22Â kcal/mol, which promotes the intercalation of conductive CPCFs into insulated PVDF matrix to form ultrathin microcapacitors. As a result, the largest dielectric constant of CPCFs/PVDF composites can reach 1583 (1Â kHz), which is about 150Â times higher than that of pure PVDF.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Part A: Applied Science and Manufacturing - Volume 87, August 2016, Pages 46-53
Journal: Composites Part A: Applied Science and Manufacturing - Volume 87, August 2016, Pages 46-53
نویسندگان
Qikai Guo, Qingzhong Xue, Tiantian Wu, Xinglong Pan, Jianqiang Zhang, Xiaofang Li, Lei Zhu,