کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7898811 1510137 2018 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Improving the Li-ion conductivity and air stability of cubic Li7La3Zr2O12 by the co-doping of Nb, Y on the Zr site
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Improving the Li-ion conductivity and air stability of cubic Li7La3Zr2O12 by the co-doping of Nb, Y on the Zr site
چکیده انگلیسی
The elements Nb and Y were simultaneously substituted to the Zr sites of an Li7La3Zr2O12 (LLZO) electrolyte to improve its Li-ion conductivity and air stability. Samples of Li7La3Zr2-2xNbxYxO12 were fabricated using a solid-state reaction method. The results show that the introduction of Nb and Y can stabilise cubic-phase LLZO. The total conductivity of Li7La3ZrNb0.5Y0.5O12 electrolyte can reach 8.29 × 10−4 S cm−1 at 30 °C when sintered at 1230 °C for only 15 h. Surprisingly, the conductivity of Li7La3ZrNb0.5Y0.5O12 can be maintained at 6.91 × 10−4 S cm−1 after exposure to air for 1.5 months, indicating excellent air stability. Furthermore, a LiFePO4/Li7La3ZrNb0.5Y0.5O12/Li cell displayed stable charge/discharge and cycling performance at ambient temperature, suggesting there is potential to use Li7La3ZrNb0.5Y0.5O12 electrolyte in Li-ion batteries. Additionally, the effects of varying the co-doping amount and dwelling time on the Li-ion conductivity of Li7La3Zr2-2xNbxYxO12 were investigated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 38, Issue 4, April 2018, Pages 1673-1678
نویسندگان
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