کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7900154 | 1510363 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Down-conversion luminescence and optical thermometric performance of Tb3+/Eu3+ doped phosphate glass
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
Tb3+/Eu3+ co-doped phosphate glasses were successfully synthesized by conventional melt-quenching method. The transmittance spectra and down-conversion optical properties were investigated by using UV-visible spectrophotometer and fluorescence spectrometer. All the glass samples show light transmittance of about 90%, and the color of luminescence could be tuned by altering the concentrations of Eu3+ ions. The decrease of the Tb3+ emission decay time in presence of Eu3+ ascertained that Tb3+â¯ââ¯Eu3+ non-radiative energy transfer happened. The research of energy transfer between Tb3+ and Eu3+ based on the Inokuti-Hirayama model revealed that an electric dipole-dipole interaction might be the predominant mechanism. Under the excitation of 378â¯nm, the temperature dependent luminescence of Tb3+/Eu3+ co-doped glasses was carefully investigated in the temperature range of 303-753â¯K. Impressively, a high absolute sensitivity Sa of 1.0%â¯Kâ1 and a high relative sensitivity Sr of 11.67â¯Ãâ¯10â3â¯Kâ1 at 753â¯K could be obtained. It is expected that the investigated glasses might be a promising candidate for solid-state lighting and optical thermometry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 484, 15 March 2018, Pages 111-117
Journal: Journal of Non-Crystalline Solids - Volume 484, 15 March 2018, Pages 111-117
نویسندگان
Yong Chen, Guohua Chen, Xiangyu Liu, Jiwen Xu, Tao Yang, Changlai Yuan, Changrong Zhou,