کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7907870 | 1510760 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Luminescence properties of Er3+ doped zirconia thin films and ZrO2/Er2O3 nanolaminates grown by atomic layer deposition
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Atomic layer deposited (ALD) ZrO2 (zirconia) thin films doped with Er3+ ions by ion implantation as well as ZrO2/Er2O3 nanolaminates were investigated at wide 5-300Â K temperature range using cathodoluminescence (CL) and photoluminescence (PL) spectroscopy under wide range of excitation energies 6-120Â eV. In the studied ALD films main emissions due to self-trapped excitons and defect centers were revealed in UV-visible (VIS) region with the excitation bands in the host absorption. In nanolaminates luminescence processes are influenced by their structure and composition. In films with the lower Er3+ ion content, typical 4f luminescence of Er3+ ions were identified being excited through energy transfer from host to doping ions. The luminescence data shows that in contrast to a few hundred nm thick ALD films, the excitonic band near 5.3-5.4Â eV are absent in the excitation spectra of nanolaminates with a typical layer thickness of 5Â nm, which do not facilitate exciton formation because of limited spatial regularity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optical Materials - Volume 74, December 2017, Pages 27-33
Journal: Optical Materials - Volume 74, December 2017, Pages 27-33
نویسندگان
Eduard Aleksanyan, Marco Kirm, Eduard Feldbach, Kaupo Kukli, Sven Lange, Ilmo Sildos, Aile Tamm,