کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7909017 | 1510788 | 2015 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Deposition of luminescent NaCl:Tm2+ thin films with a Tm concentration gradient using RF magnetron sputtering
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Luminescent thin films were deposited using magnetron sputtering of a NaCl single crystal and Tm-metal. By using a combinatorial approach, a single film with a thickness ranging from 3.1 μm to 6.9 μm and a Tm to Na ratio varying from 0.05 to 0.26 was obtained. XRD shows the formation of the simple cubic NaCl structure and SEM images display a mix of 0.50-0.75 μm and 2-3 μm cubic and needle-like structures when the substrate is not rotating during deposition. NIR transmission spectra reveal narrow absorption lines at 1134 nm and 1218 nm caused by 4f-4f absorption of divalent and trivalent Tm, respectively. Photoluminescence excitation and UV-VIS transmission spectra show broad bands between 275 nm and 700 nm, caused by the Tm2+ 4f13 â 4f125d1 transitions. Excitation into these bands results in 2F5/2 â 2F7/2 line emission by Tm2+ at 1134 nm. The broad absorption range covering the entire UV and VIS part of the solar spectrum and the absence of self-absorption of the sharp emission line makes NaCl:Tm2+ a promising material for luminescent solar concentrators as thin films on glass provided light scattering can be minimised.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optical Materials - Volume 46, August 2015, Pages 149-153
Journal: Optical Materials - Volume 46, August 2015, Pages 149-153
نویسندگان
M. de Jong, W. Kesteloo, E. van der Kolk,