کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7920130 | 1511487 | 2018 | 42 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of chelating agent on the sol-gel thermolysis synthesis of LiNiPO4 and its electrochemical properties for hybrid capacitors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
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چکیده انگلیسی
The present work reports the preparation of olivine structured LiNiPO4 nanoparticles through sol-gel thermolysis method using three different chelating agents of citric acid (LiNi-C), l-ascorbic acid (LiNi-A) and D-sorbitol (LiNi-S). The flame temperature and enthalpy change of each reaction using the chelating agent is calculated. Further, the sharp X-ray diffraction peak reveals the phase pure and high crystalline nature of the prepared LiNiPO4 nanoparticles with the space group of Pnma (62) irrespective of the chelating agents. The four possible fundamental vibrations of phosphate anion PO43â are revealed through Fourier Transform Infrared Spectroscopy (FTIR) studies. The presence of elements such as Ni, P and O and its valence state is identified through X-Ray Photoelectron Spectroscopy analysis. The spherical shape particles with the uniform size distribution of LiNi -S is observed than the LiNi-C, LiNi-A particles through FESEM analysis. The redox peaks and plateau regions in the cyclic voltammetry (CV) and Galvanostatic charge-discharge (GCD) profiles infer the dominance of battery-type charge process rather than a capacitive mechanism. As a result, LiNiPO4 exhibits a maximum specific capacitance of 417â¯Fâ¯gâ1 at 2â¯mVâ¯sâ1 and 357â¯Fâ¯gâ1 at 1â¯mAâ¯cmâ2 in 1â¯M LiOH, which enables as a suitable cathode material for hybrid supercapacitor. Also, the assembled hybrid supercapacitor delivered a high energy density of 12.5 Wh kgâ1 at 200â¯Wâ¯kgâ1 as well as a longer cycle life of 89% at a current density of 1â¯mAâ¯cmâ2 over 2000 cycles is noticed. These results infer that LiNiPO4 could be used as a novel electrode material for hybrid supercapacitor application.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 119, August 2018, Pages 183-192
Journal: Journal of Physics and Chemistry of Solids - Volume 119, August 2018, Pages 183-192
نویسندگان
N. Priyadharsini, P. Rupa Kasturi, A. Shanmugavani, S. Surendran, S. Shanmugapriya, R. Kalai Selvan,