کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7920559 | 1511492 | 2018 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural, magnetic and hyperfine characterization of ZnxFe3-xO4 nanoparticles prepared by sol-gel approach via inorganic precursors
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Structural characteristics and magnetic properties of ZnxFe3-xO4 (where Ñ
 = 0; 0.09; 0.18; 0.45; 1) nanoparticles were studied with X-ray diffraction (XRD), transmission electron microscopy (TEM), infrared spectroscopy (IR) and vibrating sample magnetometry (VSM). Oxidation of Fe2+ ions, redistribution of Zn2+ and Fe3+ ions between octahedral and tetrahedral sites, and the formation of cation vacancies in spinel-type cubic structure of the obtained ZnxFe3-x-yâ¡yO4 substitutional solid solutions were revealed by 57Fe Mössbauer spectroscopy. The nanoparticles synthesized via a modified sol-gel method using inorganic precursors have a size of 4-10 nm, single-phase composition, superparamagnetic behavior at room temperature (300 K) and a relatively hydrophilic surface to form stable aqueous suspensions. The maximum magnetization of 59 emu/g at 300 K corresponds to Zn0.18Fe2.82O4 composition. The listed features make the materials promising candidates for various biological and medical applications such as contrast-enhanced magnetic resonance imaging, hyperthermia of pathological tissues, controlled drug release, and separation of nucleic acids.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 114, March 2018, Pages 64-70
Journal: Journal of Physics and Chemistry of Solids - Volume 114, March 2018, Pages 64-70
نویسندگان
Dzmitry Kotsikau, Vladimir Pankov, Elena Petrova, Valentin Natarov, Dmitry Filimonov, Konstantin Pokholok,