کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7921278 | 1511747 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Erbium doped sodium magnesium boro-tellurite glass: Stability and Judd-Ofelt analysis
ترجمه فارسی عنوان
شیشه اکسید بوریک تلوریت منیزیم سدیم اربیوم: تجزیه و تحلیل پایداری و جود-اوتالت
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
چکیده انگلیسی
Understanding the influence of rare earth ions in improving the optical properties of glasses are important in order to extend in advanced application. The behavior of series of Er3+ (1.0-2.0â¯mol %) doped B2O3-TeO2-MgO-Na2O glasses synthesized by conventional melt-quenching technique are explored. X-ray diffraction (XRD) pattern confirms the amorphous nature of the prepared glass sample. The DTA data asserts that the addition of Er3+ increased the thermal stability from 142 to 207â¯Â°C. The UV-VIS-NIR spectra reveal ten absorption bands centered at 4G11/2, 2H9/2, 4F5/2,4F7/2, 2H11/2, 4S3/2,4F9/2, 4I9/2, 4I11/2 and 4I13/2 from ground state of 4I15/2. The Judd-Ofelt Ω2 parameter values gradually decreases with the increase of erbium ions concentration from 0.5 to 2â¯mol %. From the Judd-Ofelt parameters (Ωt), transition probabilities (A), branching ratios (βR) of various transitions and their radiative lifetimes (Ïrad) are calculated. The up-conversion emission spectra of Er3+ exhibit four peaks centered at 538â¯nm, 554â¯nm, 653â¯nm and 822â¯nm assigned to 2H11/2â¯ââ¯4I15/2, 4S3/2â¯ââ¯4I15/2,4F9/2â¯ââ¯4I15/2 and 4I9/2â¯ââ¯4I15/2 transitions respectively in all samples. The maximum enhancement is evidenced at 1.5â¯mol% of Er2O3 by a factor of 3.11, 1.88 and 2.80 times for 2H11/2â¯ââ¯4I15/2, 4S3/2â¯ââ¯4I15/2 and 4I9/2â¯ââ¯4I15/2 transitions respectively. A schematic energy level diagram is proposed. The effective band width at half maximum (FWHM) (Îλeff), stimulated emission cross-section (δPE) and the product of δPEÃFWHM for 4S3/2 transitions of the glasses have also been studied and reported.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 216, 1 September 2018, Pages 177-185
Journal: Materials Chemistry and Physics - Volume 216, 1 September 2018, Pages 177-185
نویسندگان
Nur Liyana Amiar Rodin, M.R. Sahar,