کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7921293 | 1511746 | 2018 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The effect of mixed alkali on structural changes and ionic migration characteristics in zinc borate glasses
ترجمه فارسی عنوان
اثر قلیا مخلوط بر تغییرات ساختاری و ویژگی های مهاجرت یونی در عینک بورات روی
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
چکیده انگلیسی
The effect of mixed alkali on structural changes and ionic migration characteristics have been investigated in zinc borate glasses system with composition 5Al2O3-15ZnO-(15-x)K2O-xNa2O-65B2O3(xâ¯=â¯0,3,6,9,12,15mol%). The thermal properties including glass transition temperature (Tg), thermal expansion coefficient (α) and dilatometric softening temperature (Td) were determined by differential scanning calorimeter (DSC) and dilatometer. The ionic migration characteristics were investigated through dc conductivity and chemical stability, determined by electrochemical workstation and normalized mass losses (N(i)). And the glass structure was characterized by Fourier transform infrared spectroscopy, to explain the relationship between structure and properties. As the ratio of [Na2O]/([K2O]+[Na2O])(mol/mol) increase, the glass transition temperature (Tg), dilatometric softening temperature (Td), dc conductivity(Ïdc) and normalized mass losses (N(i)) of glass exhibit a nonlinear variation, deviate negatively from linearity, meanwhile thermal expansion coefficient (α) varies nonlinearly and deviates positively from linearity. From the FTIR studies the N4 values (fraction of tetrahedral coordinated boron atoms) exhibit a nonlinear variation, deviates negatively from linearity. These data clearly indicated the presence of strong mixed alkali effect (MAE) in the zinc borate glass system, and the MAE changes glass structure and inhibits ion migration.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 217, 15 September 2018, Pages 519-526
Journal: Materials Chemistry and Physics - Volume 217, 15 September 2018, Pages 519-526
نویسندگان
Ao Li, Mitang Wang, Mei Li, Zhaogang Liu, Yanhong Hu, Xiaowei Zhang,