کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7921695 | 1511751 | 2018 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Determination of thermal expansion of KCaI3 using in-situ high temperature powder X-ray diffraction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
KCaI3:Eu single crystals exhibit favorable scintillation properties and have potential for use in domestic security applications requiring radioisotope identification. The anisotropic thermal expansion of the orthorhombic unit cell of this perovskite-type scintillator has been investigated using in-situ high temperature X-ray diffraction on powdered samples. Samples from single crystals of both pure and Eu-doped KCaI3 grown by the Bridgman method were used for comparison. Expansion with temperature along the b-axis is greatest with an average linear coefficient of thermal expansion of â (41-46) x 10â6â¯Kâ1 resulting from the weaker bonding between alternating layers of K and Ca parallel to the b-axis. Thermal expansion in each of the KCaI3 samples has the highest degree of anisotropy with respect to the b and c axis with ratio á¾±b/á¾±c of 1.4-1.5. Additionally, we identify the predominant cleavage plane in KCaI3 as (0 -3 -1) based upon Laue reflection imaging.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 212, 15 June 2018, Pages 161-166
Journal: Materials Chemistry and Physics - Volume 212, 15 June 2018, Pages 161-166
نویسندگان
Adam C. Lindsey, Matthew Loyd, Maulik K. Patel, Ryan Rawl, Haidong Zhou, Merry Koschan, Charles L. Melcher, Mariya Zhuravleva,