کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7921826 | 1511751 | 2018 | 27 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural and optical properties of Cr3+ embedded in a P2O5-B2O3-ZnO-BaF2-AlF3 fluoroborophosphate glasses
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Structural and optical properties of Cr3+ embedded in a P2O5-B2O3-ZnO-BaF2-AlF3 fluoroborophosphate glasses Structural and optical properties of Cr3+ embedded in a P2O5-B2O3-ZnO-BaF2-AlF3 fluoroborophosphate glasses](/preview/png/7921826.png)
چکیده انگلیسی
A new fluoroborophosphate glass doped with different amount of CrF3 were prepared via the melt-quenching method. These glasses were characterized by several techniques. The amorphous nature of the glass was evidenced by X-ray diffraction. Raman and FTIR were used to determine the functional groups composing the glass network. It was demonstrated the formation of B-O-P bond which replace some of the P-O-P bond and ensure the bonding of phosphorus and boron groups. Electron paramagnetic resonance (EPR), optical absorption and photoluminescence (PL) investigation have shown that Cr3+ ions have a preference to be located at weak field with distorted octahedral sites and they are mainly dispersed in phosphorus rich environment with fluorine or mixed fluorine/oxygen surrounding anions. Cr3+ sites dispersion was also evidenced by analyzing the temperature dependence of the PL spectra and the PL decay.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 212, 15 June 2018, Pages 461-470
Journal: Materials Chemistry and Physics - Volume 212, 15 June 2018, Pages 461-470
نویسندگان
N. Saad, M. Haouari, A. Bulou, A. Hadi Kassiba, H. Ben Ouada,