کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7922557 1511785 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and effect of annealing temperature on the structural, magnetic and photocatalytic properties of (La0.5Bi0.2Ba0.2Mn0.1)FeO(3−δ)
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
Synthesis and effect of annealing temperature on the structural, magnetic and photocatalytic properties of (La0.5Bi0.2Ba0.2Mn0.1)FeO(3−δ)
چکیده انگلیسی
Novel La0.5Bi0.2Ba0.2Mn0.1FeO3−δ, with a perovskite-like structure, was synthesized by using the citric acid sol-gel route. The powder was precalcined at 400 °C and then separate portions were annealed at temperatures of 500, 600, 700, 800 and 900 °C. Transmission electron microscopy and powder X-ray diffraction analysis of the powders showed that they contain crystalline rhombohedral perovskite-type nanoparticles. The BET specific surface areas ranged between 4.19 and 27.8 m2 g−1, decreasing with increasing annealing temperature. Vibrating sample magnetometer analysis of the hysteresis loops showed an increase in coercive field with increasing annealing temperature. Very large coercive fields of about 5.60 kOe were obtained for samples annealed at 900 °C. This could prove useful in making magnetic recording materials. Photoluminescence spectroscopy showed that all the powders were active in the visible region and could be useful for visible light photodegradation of pollutants. The powders were all screened for photocatalytic activity against an organic dye (rhodamine B) in the visible region of the solar spectrum and the photocatalytic activities were good particularly for powders annealed at 900 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 178, 1 August 2016, Pages 196-203
نویسندگان
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